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has the bent shape as shown in Fig. 10.13. As a result, HTP of cis-m-azo-9 is higher than that of trans-m-azo-9. As mentioned in the preceding section, the anisotropy in the molecular shape in uences signi cantly HTP of chiral compounds. Thus, to discuss the structural effect on the photochemical change in HTP, the molecular aspect ratio, L/D, was estimated with MOPAC/PM3 method. The molecular aspect ratios of the chiral azobenzene compounds in their isomeric states are given in Table 10.3. The data reveal that HTP of the chiral azobenzene compounds in both the isomeric states

At the top, spanning the full width, is the blog header, which in fact is the headerphp file Underneath is the actual blog area, with the content to the left (index php) and the sidebar to the right (sidebarphp) Finally, there is a footer to wrap it up, using the footerphp template file This setup is not mandatory; you can change it, exclude parts of it, or expand it further It is, however, a very common setup, one that the default WordPress theme as well as the Notes Blog Core theme adheres to You ll see a lot of themes using template files in this manner if you look around, but it is in no way the only way to do things It is just common, that s all..

trans-m-Azo-8

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There s a lot of code ahead. Most of it is pretty simple, and I ll be keeping things as conceptual and straightforward as possible. That way, the actual usage of the various template tags and functions come into play, rather than being obscured by other code that won t matter in the long run. That being said, you should be aware that the following examples include localization tags and both template and conditional tags that you may not be entirely familiar with. Most of the latter two categories speak for themselves, but localization may be a bit harder to grasp. You ll get to the details of that later on, but for now you only need to know that when you localize, you either wrap the text/code within _e() or __(). You use __() within PHP code, while the former is more or less used anywhere. Add a textdomain and you ve got the basics, like this:

cis-m-Azo-8

trans-m-Azo-9

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Both _e() and __() rely on the premise that the text or code you can localize gets passed first, and then the textdomain that should be used. In the Notes Blog Core examples, the textdomain is called 'notesblog', so it would look like this:

cis-m-Azo-9

Now that the basics are out of the way, it s time to get our hands dirty!

depends on their molecular aspect ratio with an exception of o-azo-9 and azo-10. The molecules with larger L/D exhibited larger HTP, regardless of trans form and cis form. However, the molecular aspect ratio as well as HTP of the chiral azobenzene compounds are changed by trans cis photoisomerization. Therefore, it is worthwhile to explore the effects of change in the shapes of the chiral azobenzene molecules on their HTP, to develop effective phototrigger for photomodulation of helical structure. In Fig. 10.14, photochemical change in HTP, D(HTP), is plotted as a function of photochemical change in molecular aspect ratio, D(L/D); here D(HTP)=HTPcis HTPtrans; D(L/D)=(L/D)cis (L/D)trans. It is observed that D(HTP) of the chiral azobenzene compounds is dependent on their D(L/D). The relation of D(HTP) and D(L/D) is classi ed into three groups: Gr-A (azo-1, azo-4, azo-5), Gr-B (azo-6 and

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